SAVAGE-TAYLOR CHEMICALS INC -- SULFURIC ACID -- 6810-00N093089
===================== Product Identification ===================== Product ID:SULFURIC ACID MSDS Date:05/01/1999 FSC:6810 NIIN:00N093089 Status Code:A === Responsible Party === Company Name:SAVAGE-TAYLOR CHEMICALS INC Address:215 FRANKLIN ST, SUITE 400 City:CLARKSVILLE State:TN ZIP:37040 Country:US Info Phone Num:931-553-8585 Emergency Phone Num:800-424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:TO385 === Contractor Identification === Company Name:INDUSTRIAL CHEMICALS, INC (804-275-9292) Address:2540 BELLWOOD ROAD Box:City:RICHMOND State:VA ZIP:23237 Country:US Phone:804-275-9292;757-624-5369 CAGE:0K073 Company Name:SAVAGE-TAYLOR CHEMICALS INC Address:215 FRANKLIN ST, SUITE 400 Box:City:CLARKSVILLE State:TN ZIP:37040 Country:US Phone:931-553-8585 CAGE:TO385 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID - 86 BAUME CAS:7664-93-9 RTECS #:WS5600000 = Wt:93.19 OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 ACGIH STEL:3 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: 3RD DEGREE BURNS. SEVERE RESPIRATORY, SKIN AND EYE IRRITANT. CHRONIC: BRONCHITIS. LARYNGEAL AND PULMONARY EDEMA MAY RESULT. ANIMAL TESTING INDICATES THAT THIS COMPOUND DOES NOT HAVE CARCINOGENI C; MUTAGENIC, EMBRYOTOXIC, OR REPRODUCTIVE EFFECTS. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) CLASSIFIES " OCCUPATIONAL EXPOSURES TO STRONG INORGANIC ACID MISTS CONTAINING SULFURIC ACID" AS A CATEGORY 1 CARCINOGEN, A SUBSTANCE THAT IS "CARCINOGENIC TO HUMANS". THE BASIS FOR IARC CLASSIFICATION RESTS ON SEVERAL EPIDEMIOLOGY STUDIES WHICH DID NOT ACCOUNT FOR EXPOSURE TO OTHER SUBSTANCES , (EFTS OF OVEREXP) Explanation of Carcinogenicity:SULFURIC ACID: IARC MONOGRAPHS ON THE EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOLUME 54, PAGE 41, 1992: GROUP 1. Effects of Overexposure:HLTH HAZ: SOME KNOWN TO BE ANIMAL OR POTENTIAL HUMAN CARCINOGENS, SOCIAL INFLUENCES (SMOKING OR ALCOHOL CONSUMPTION), AND INCLUDED SMALL NUMBERS OF SUBJECTS. SIGNS AND SYMPTOMS OF OVEREXPOSURE: IRRITA TION OF MUCOUS MEMBRANES. COUGHING, SNEEZING, TIGHTNESS OF CHEST, DIFFICULTY IN BREATHING. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY DISEASE. ======================= First Aid Measures ======================= First Aid:SPEED IN REMOVING ACID IS ESSENTIAL. TREAT MOST URGENT SYMPTOMS FIRST: CESSATION OF BREATHING, EYE INJURY, SKIN CNTCT, SHOCK. SEEK MED ASSISTANCE EVEN IF INJURY APPEARS SLIGHT. GIVE MD DETAILED ACCOUN T OF INCIDENT. INHAL: REMOVE FROM EXPOS. GIVE OXYGEN IF BRTHG IS DFCLT. BEGIN ARTF RESP/CPR, IF INDICATED. EYES: FLUSH IMMED W/LRG AMTS OF H*2O FOR AT LEAST 15 MIN HOLD EYELIDS OPEN DURING FLUSHING. S KIN: FLUSH AREA IMMED W/LRG AMTS OF H*2O. REMOVE ALL CONTAMD CLTHG & SHOES (THIS CAN BE DONE WHILE UNDER SHOWER). INGEST: IF CONSCIOUS, GIVE LRG AMTS OF MILK, MILK OF MAGNESIA, TABLE OIL/FRESH EGGS. G IVE H*2O WHEN NOTHING ELSE (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:SMALL FIRES: DRY CHEMICAL, CO*2 OR HALON. LARGE FIRES: WATER FOG. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . DO NOT DIRECT WATER INTO ACID TANKS. COOL OUTSIDE OF TANK WITH WATER. Unusual Fire/Explosion Hazard:SULFURIC ACID WILL NOT BURN BUT CAN START FIRE W/ORG MATL, NITRATES, CARBIDES, CHLORATES & METAL POWDERS, HYDROGEN GAS CAN FORM WHEN ACID CONTACTS MOST METALS. HYDROGEN MAY ACCUM IN CNTNRS, AVOID IGNI T, SOURCES. SPILL OVER INTO SEWERS MAY GENERATE HYDROGEN GAS/ SULFIDES. ADDITION OF H*2O TO ACID CAUSES (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:WEAR FULL ACID-PROTECTIVE GEAR. REMOVE SOURCES OF IGNITION. NEUTRALIZE WITH LIME IS OR SODA ASH. DIKE LARGE SPILLS. NOTIFY AUTHORITIES, IF REQUIRED, IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULAT IONS. Neutralizing Agent:NEUTRALIZE WIHT LIME OR SODA ASH. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE NEAR ORGANIC OR OTHER INCOMPATIBLE MATERIALS. HYDROGEN MAY BE GENERATED INSIDE TANKS. AVOID IGNITION SOURCES AND HIGH HEAT. Other Precautions:NEVER ADD WATER TO CONTAINERS OF ACID. BEWARE OF ACID REACTION IN SEWERS THAT MAY PRODUCE FLAMMABLE HYDROGEN GAS OR HYDROGAN SULFIDE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE AS NECESSARY TO CONTROL EXPOSURE BELOW APPLICABLE EXPOSURE LIMITS. FOR CONC UP TO 10 TIMES TLV, USE NIOSH APPROVED HALF OR FULL AIR-PURIFYING RESP W/ACID GAS CARTRIDGES. FOR HIGHER CONCENTRATIONS, CONSULT A PROFESSIONAL INDUSTRIAL HYGIENIST. USE ALL RESPIRATORY PROTECTION IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE (I.E 29 CFR 1910.134). Ventilation:LOCAL EHXAUST: AN APPROPRIATE FOR POINT SOURCES. MECHANICAL (GENERAL): VENTILATE STORAGE TANKS BEORE ENTRY. Protective Gloves:IMPERMEABLE ACID RESISTANT GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH FACESHIELD . Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . IMPERMEABLE ACID RESISTANT SAFETY SHOES/BOOTS, RUBBER APRON OR FULL SUIT IF SPLASHES LIKELY. Work Hygienic Practices:PROVIDE SAFETY SHOWERS & EYE WASH STATION NEAR WORK SITE. TRAIN EMPLOYEES IN SAFE CHEM HANDLING & GOOD HYGIENE PROCEDURES. EVALUATE WORKER EXPOS TO HAZ MATL & MIN EXPOS THROUGH IMPLEMENTATION OF(SUPDAT) Supplemental Safety and Health FIRST AID PROC: AVAILABLE, RINSE MOUTH OFTEN. DO NOT INDUCE VOMIT. EXPLO HAZ: HEAT & POTENTIALLY EXPLOSIVE MIXT. HYGIENE PRACT: FEASIBLE ENGINEERING & ADMINISTRATIVE CONTROLS, UTILIZE PERS PROT EQUIP IF OTHER CONTROLS ARE NOT FEASIBLE/AS REDUNDANT CONTROL MEASURE. ================== Physical/Chemical Properties ================== Boiling Pt:=290.C, 554.F Melt/Freeze Pt:=-32.C, -25.6F Vapor Pres:(MMHG) 1 @ 146%C (295%F) Vapor Density:8.4(AIR=1) Spec Gravity:1.84@16% (60%F) (H*2O=1) Evaporation Rate & Reference:N/A (BUTYL ACETATE =1) Solubility in Water:COMPLETE Appearance and Odor:COLORLESS TO BROWNISH OILY LIQUID. ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CNTCT W/ METAL POWDERS & SPECIFICALLY TOXIC MATLS SHOULD AS CYANIDE. CNTCT W/THESE ORGANIC MATLS, NITRATES, CARBIDES & CHLORATES MAY CAUSE IGNITION/GENERATION OF TOX GASES. NEVER ADD H*2O TO ACID DILUTION IS DESIRED, Stability Condition to Avoid:N/A. Hazardous Decomposition Products:SULFUR OXIDES ARE FORMED AT HIGH TEMPERATURES. ACID REACTS WITH INCOMPATIBLE SUBSTANCES TO FORM HIGHLY TOXIC HYDROGEN CYANIDE AND/OR HYDROGEN SULFIDE GAS. Conditions to Avoid Polymerization:WILL NOT OCCUR. ===================== Ecological Information ===================== Ecological:N/P --WASTE DISP METH: PROVINCIAL AND LOCAL REGULATORY AUTHORITIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. DEFINED AS A "HAZARDOUS WASTE" UNDER EPA (40 CFR 261) - EPA HAZARDOUS WASTE NO. D001. SUBJEC T TO THE LAND DISPOSAL RESTRICTIONS (40CFR 268) AND MUST BE MANAGED ACCORDINGLY. --OTHER INFO: OXYG GAS. OTHER CHEMS WHICH CAN BE USED TO BREAK DOWN CALCIUM HYPOCHLORITE ARE SODIUM SULFATE & SODIUM B ISULFITE. ONCE CALCIUM HYPOCHLORITE IS REDUCED, REMAINING SOLN SHOULD BE NEUT CAUTIOUSLY W/DILUTE HYDROCHLORIC/SULFURIC ACID. LG SPILLS: CONT FIRE & EMER SERVICES & SUPPLIER FOR ADVICE. NOTIFY GOVNMEN T ENVIR & OCCUP HLTH & SFTY AGENCIES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT FEDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:SPECIAL SHIPPING REQUIREMENTS: CANADIAN TRANSPORTATION OF DANGEROUS GOODS (TDG). CLASSIFICATION: 5.1- (OXIDIZING SUBSTANCE). 9.2 - (SUBSTANCE HAZS TO ENVIRONMENT). UN: 1748,2880. PACKING GROUP: II, LA BEL: OXIDIZER, SPECIAL PROVISIONS: 109,REGULATED LIMIT: 5 KG. U S DEPARTMENT OF TRANSPORT (DOT) HAZ MATLS SHIPPING INFORMATION (49 CFR) 5. HAZARDS CLASS OR DIVISION: 5.1 - (OXIDIZER). UN: 174,2880, PA CKING GROUP: II, LABEL: OXIDIZER, REPORTABLE QUANTITY (RQ): 10 LBS. IN CASE OF TRANSPORTATION EMER: IN CANADA, CONTACT: CANUTEC (613) 996-6666. IN US, CONTACT: CHEMTREC (800) 424-9300. ALSO CONTACT AP PROPRIATE LOCAL & FED AUTHORITIES. ===================== Regulatory Information ===================== SARA Title III Information:SUPERFUND "REPORTABLE QUANTITY" CHEMICAL: RCRA/CERCLA STANDARDS (40 CFR PART 302): "HAZARDOUS SUBSTANCE" DESIGNATION: RCRA WASTE NO: NONE DESIGNATED. CATEGORY: A REPORTABLE QUANTITY (RQ): 10 LBS (4.54 KG). EPA CLEAN WATER ACT (40 CFR PARTS 116,117): "HAZARDOUS SUBSTANCE" DESIGNATION REPORTABLE QUANTITY (RQ): CATEGORY A-10 LBS (4.5 KG). Federal Regulatory Information:U S OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA) HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) "HAZARDOUS MATERIAL" DESIGNATION. EPA FIFRA 1988 - FEDERAL REGISTER 54,7740,89 (FEREAC). PESTI CIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION. ANSI/NSF STANDARD 60: MAXIMUM CONCENTRATION FOR POTABLE WATER TREATMENT - 46 MG/L. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.